User manual FELLOWES 99794 DUSTER 10OZ-CANADA

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[. . . ] Keep people away from such vapors without selfcontained breathing apparatus. SIGNS AND SYMPTOMS OF OVEREXPOSURE EYES: Can cause severe eye irritation. SKIN: Exposure to rapidly expanding gas or vaporizing liquid may cause frostbite ("cold" burn). INHALATION: High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis and loss of consciousness). [. . . ] FIRE FIGHTING EQUIPMENT: As in any fire, wear self-contained breathing apparatus pressure-demand, (MSHA/NIOSH approved or equivalent) and full protective gear. RELEASE NOTES: Spills and releases may have to be reported to Federal and/or local authorities. 7. HANDLING AND STORAGE HANDLING: Follow standard safety precautions for handling and use of compressed gas cylinders. STORAGE: Store in a cool place in original container and protect from sunlight. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES: OSHA HAZARDOUS COMPONENTS (29 CFR 1910. 1200) EXPOSURE LIMITS OSHA PEL ACGIH TLV Supplier OEL ppm 1, 000 [1] ppm mg/m3 ppm mg/m3 1, 1, 1, 2-Tetrafluoroethane (HFC-134a) TWA NE NE OSHA TABLE COMMENTS: 1. * (AEL)=Acceptable Exposure Limit as established by the manufacture mg/m 3 ENGINEERING CONTROLS: Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Wear safety glasses with side shields (or goggles) and a face shield. General work clothing and gloves (leather) should provide adequate protection. If prolonged contact with the liquid or gas is anticipated, insulated gloves constructed of PVA, neoprene or butyl rubber should be used. Any contaminated clothing should be promptly removed and washed before reuse. RESPIRATORY: A respiratory protection program that meets OSHA 1910. 134 and ANSI Z88. 2 requirements must be followed whenever workplace conditions warrant a respirator's use. MSDS Ref. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Gas ODOR: Faint ethereal odor pH: Neutral PERCENT VOLATILE: 100 at 20°C (68°F) VAPOR PRESSURE: 85. 8 psi at 21. 1°C (70°F) VAPOR DENSITY: 3. 5 (Air=1) BOILING POINT: -26. 2°C (-15. 1°F) FREEZING POINT: -101°C (-149. 8°F) SOLUBILITY IN WATER: Negligible EVAPORATION RATE: >1 (CCL4=1) SPECIFIC GRAVITY: 1. 22 (water=1) at 20°C (68°F) 10. STABILITY AND REACTIVITY STABLE: YES HAZARDOUS POLYMERIZATION: NO CONDITIONS TO AVOID: Stable. HAZARDOUS DECOMPOSITION PRODUCTS: May form hydrochloric and hydrofluoric acids - possibly carbonyl halides, when exposed to high temperatures. INCOMPATIBLE MATERIALS: Chemically active metals: potassium, calcium, powdered aluminum, magnesium and zinc. 11. TOXICOLOGICAL INFORMATION ACUTE INHALATION LC : >500000 ppm, 4-hour 50 SENSITIZATION: Cardiac sensitization threshold (dog) 80, 000 ppm. SUBCHRONIC: Subchronic inhalation (rat) NOEL - 50, 000 ppm Chronic NOEL - 10, 000 ppm MUTAGENICITY: Collective data indicate non-mutagenic. ECOLOGICAL INFORMATION ENVIRONMENTAL DATA: Degradability (BOD): This material is a gas at room temperature; therefore, it is unlikely to remain in water. [. . . ] COMMENTS: WARNING: Contains 1, 1, 1, 2-tetrafluoroethane (HFC-134a), a greenhouse gas which may contribute to global warming. 16. Pillon TITLE: Chemist REVISION SUMMARY Revision #: 1 This MSDS replaces the December 02, 2002 MSDS. Any changes in information are as follows: In Section 15 EEC Symbol Id. EEC Risk Phrase Codes HMIS RATING HEALTH: FLAMMABILITY: PHYSICAL HAZARD: PERSONAL PROTECTION: NFPA CODES 1 1 0 1 2 0 DATA SOURCES: Code of Federal Regulations (CFR) The Sigma-Aldrich Library of Regulatory and Safety Data OSHA Hazard Communication Standard (29CFR1910. 1200) MSDS Ref. [. . . ]

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